Very low water solubility 2. It only takes a minute to sign up. http://periodic-table-of-elements.org/SOLUBILITY. Spectral range not as good as the soluble materials 3. There are few exceptions to this rule. At the same time, the BaF2 is a very different substance than Ba 2+ and F-.Knowing the solubility rules can help you determine whether BaF2 will dissolve in water and dissociate into ions (see https://youtu.be/zffVKN6tm7k). Thus, it is insoluble in water. Calculate its Ksp. Question = Is SCl6polar or nonpolar ? Salts containing the ammonium ion (NH4+) are also soluble. I was going through JD Lee and I found certain contradictory statements. Divide the mass of the compound by the mass of the solvent and then multiply by 100 g to calculate the solubility in g/100g . [12] It can be also used for detection of high-energy (10150 MeV) neutrons, using pulse shape discrimination techniques to separate them from simultaneously occurring gamma photons. Retrieved from https://www.thoughtco.com/solubility-product-from-solubility-problem-609530. How to notate a grace note at the start of a bar with lilypond?
Barium Fluoride Formula: Definition,Concepts and Examples Question = Is C2H6Opolar or nonpolar ? By clicking Post Your Answer, you agree to our terms of service, privacy policy and cookie policy. Step-by-step solution
13.2: Saturated Solutions and Solubility - Chemistry LibreTexts Barium fluoride is an inorganic compound with the formula Ba F 2. 7 10 - 6 at 25C. So, the minimum solubility is in the middle of the series. Suppose we have a solution that is 0.100 M in CI- and in. The solubility rules are only for ionic solids' ability to dissolve in water. Solubility depends entirely on the physical and chemical properties of the solute and solvent, and isnt affected by the rate of solution. The 5 Strategies You Must Be Using to Improve 160+ SAT Points, How to Get a Perfect 1600, by a Perfect Scorer, Free Complete Official SAT Practice Tests. Answer = IF4- isNonpolar What is polarand non-polar? Hydroxide salts of Group II elements (Ca, Sr, and Ba) are slightly soluble. Learn more about Stack Overflow the company, and our products. Solubility in / Miscibility with Water at 25 C (77 F): 1.2 g/l Soluble Partition coefficient (n-octanol/water): No data available. A saturated solution of BaF2 at 25C is prepared by equilibrating solid BaF2 with water. Calculate the concentration of fluoride ion in the solution after addition of .
Barium Fluoride | AMERICAN ELEMENTS Question: Is BaF2 ( Barium fluoride ) Soluble or Insoluble in water ? 6 What makes BaF2 soluble or insoluble in water? hbspt.cta.load(360031, '4efd5fbd-40d7-4b12-8674-6c4f312edd05', {}); Have any questions about this article or other topics? Everything you need for your studies in one place. What is the actual order of solubility of alkaline earth metal fluorides? Question = Is IF4-polar or nonpolar ? A solution is considered saturated when adding additional solute does not increase the concentration of the solution. This is partly why it's important to follow the solubility rules closely.
Answer = SCl6 is Polar What is polarand non-polar? (aq) + CO3 2- (aq). It is also used in metallurgy, as a molten bath for refining aluminium. (2020, January 29). How do you get out of a corner when plotting yourself into a corner. Exceptions: NH4+, Li+, Na+, K+- most carbonates (CO32-) are insoluble. 3 Ratings (17 Votes) 3. Get the latest articles and test prep tips! Though I was excited to watch the salt seem to disappear I definitely didnt understand the intricacies of solubility. Which of these salts will be more soluble in an acidic solution than in water? Stack Exchange network consists of 181 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share their knowledge, and build their careers. Given: solubility in g/100 mL. Free samples program. Is calcium oxide an ionic or covalent bond . AgCl Powdered NaF is then dissolved in the solution until the solubility of BaF2 is 1.0% of that in H2O alone. The order of solubility of the alkaline earth fluorides is, after $\ce{BeF2}$ : $\ce{BeF2}$ itself is mentioned as infinitely soluble in water. When you are working on chemical equations or building a hypothesis, solubility rules are helpful in predicting the end states of the substances involved.
Carbonates are frequently insoluble. Need more help with this topic? Very subject to thermal shock 2. It is based on the difference in solubility between silver chloride. Salts containing Cl -, Br -, or I - are generally soluble. ThoughtCo. Answer: BaF2 ( Barium fluoride ) is Soluble in water What is Soluble and Insoluble ? BeF2 is soluble in water due to evolution of large hydration energy, when it is dissolved in water, which is sufficient enough to overcome the lattice energy of the Berylium Flouride, as for a compound to be soluble in water, the lattice energy of the compound must be less than the hydration energy evolved upon dissolution in water. Group II carbonates (CaCO3, SrCO3, and BaCO3) are insoluble, as are FeCO3 and PbCO3. [9] Under standard conditions it adopts the fluorite structure and at high pressure the PbCl2 structure. I didn't understand why cl didn't react with H? Thanks for contributing an answer to Chemistry Stack Exchange! Stop procrastinating with our smart planner features. The concentration of fluoride ions in the solution is as follows: [F ]=2s. ThoughtCo, Jan. 29, 2020, thoughtco.com/solubility-product-from-solubility-problem-609530. [13] Its nonlinearity violates VSEPR theory.
Barium fluoride | BaF2 - PubChem Which amongst the following respresents a chemical change. Start with our study notes for IB Chemistry. Barium fluoride is used as a preopacifying agent and in enamel and glazing frits production. The solubility of a substance fundamentally depends on the physical and chemical properties of the solute and solvent as well as on temperature, pressure and the pH of the solution. Solubility Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a solid, liquid, or gaseous solvent.
PDF BaF Barium Fluoride - Spectral Systems, LLC Will BaF2 dissolve in water?
What is the molar solubility of barium fluoride (BaF2) in water? The I am struggling calculating the solubility of BaF2 at pH of 4, whats given is the following: BaF2=Ba+2F Ksp=1.7*10^-6 . The solubility is equal to the concentration of the Ba ions in solution.solubility = [Ba+] = 7.94 x 10-3 M[F-] = 2 [Ba+]Ksp = [Ba+][F-]2Ksp = ([Ba+])(2 [Ba+])2Ksp = 4[Ba+]3Ksp = 4(7.94 x 10-3 M)3Ksp = 4(5 x 10-7)Ksp = 2 x 10-6. Very good index match to water Disadvantages 1. Salts containing Group I elements (Li+, Na+, K+, Cs+, Rb+) are soluble . The rate of solution refers to how quickly a substance dissolves, and is separate from solubility. SAT is a registered trademark of the College Entrance Examination BoardTM. What is the molar solubility of barium fluoride in 0.15 M NaF at 25C? Substances on this list are given by their elemental names. As more acid is added to a suspension of Mg(OH)2, the equilibrium shown in Equation 16.4. You can use dozens of filters and search criteria to find the perfect person for your needs. Use Coupon: CART20 and get 20% off on all online Study Material, Complete Your Registration (Step 2 of 2 ), Sit and relax as our customer representative will contact you within 1 business day. The multiplication of ions of a specific compound when particularly dissolved in an aqueous solution becomes equivalent to solubility product. The solubility-product constant for BaF2 is 1.7x 10-6 at 25C. Above ca. To subscribe to this RSS feed, copy and paste this URL into your RSS reader. The solubility-product constant for BaF2 is 1.7x 10-6 at 25C. Barium fluoride is transparent from the ultraviolet to the infrared, from 150 to 200 nm to 1111.5m. Hydroxide salts of transition metals and Al3+ are insoluble. Exceptions: Group 1 and NH4+Note: Rules at the top supersede any lower rules.---We can also look a Solubility Table (https://youtu.be/b0pDquyGSdk). Helmenstine, Todd.
Does a KitchenAid have a juicer attachment? It is a colorless solid that occurs in nature as the rare mineral frankdicksonite. To do so, first prepare an ICE (Initial, Change, and Equilibrium) table showing the equilibrium concentrations of the ions in terms of x, the molar solubility of the compound.Then, plug these expressions into the solubility-product expression for the compound and solve for the value of x. b. To show that they are dissolved in water we can write (aq) after each. Asking for help, clarification, or responding to other answers. The extent of the solubility of a substance in a specific solvent is measured as the saturation concentration, where adding more solute does not increase the concentration of the solution and begins to precipitate the excess amount of solute. 500C, BaF2 is corroded by moisture, but in dry environments it can be used up to 800C. I transcribed for you this time but might be less generous in the future. He holds bachelor's degrees in both physics and mathematics. lattice energy is less than that of the energy of hydration. Thus, s=21[F ]. 1.7 x 10^-6 One of our academic counsellors will contact you within 1 working day. The answer is that it is slightly soluble in water. If you continue to use this site we will assume that you are happy with it. Lets do an example: The solubility of Ag2CrO4 in water is 1.31 x 10-4 moles/L. 1. While many compounds are partially or mostly insoluble, there is no substance that is completely insoluble in water, meaning that it can't dissolve at all. This problem has been solved! Arsenic, antimony, bismuth, and lead sulfides are also insoluble. Note that a very small amount of BaF2 would dissolve but very little. The answer that Calcium fluoride is insoluble in water. What is the molar solubility of BaF2 in water? Term contracts & credit cards/PayPal accepted. Given: solubility in g/100 mL.
Which of the following is least soluble? ( a)Bef2 (b - Careers360 and we put it in some distilled water, the solid is going to reach an equilibrium with the ions in solution. In some solvents, when heated the molecules vibrate faster and are able to break apart the solute. Question = Is SbCl5 ( Antimony pentachloride ) polar or nonpolar ? For help with net ionic equations see https://youtu.be/PXRH_IrN11Y .If you need to know how to balance chemical reactions, see my complete tutorial on balancing all types of chemical equations:Balancing Equations in 5 Easy Steps: https://youtu.be/zmdxMlb88FsMore Practice Balancing: https://youtu.be/Qci7hiBy7EQDrawing/writing done in InkScape. Question = Is SiCl2F2polar or nonpolar ? chemistry.stackexchange.com/questions/127687/, We've added a "Necessary cookies only" option to the cookie consent popup. Additionally, a solution is miscible when it can be mixed together at any ratio- this mainly applies to liquids, like ethanol, C2H5OH, and water, H2O. There are essentially no HF molecules. Rule 4 says that silvers (Ag) are frequently insoluble, but rule 3 says that chlorates (Cl) are soluble. Question = Is if4+polar or nonpolar ? Solubility is a substance's ability to be dissolved. For each of the following ionic compounds, state whether the solubility will increase, decrease, or remain unchanged as a solution at pH 7 is made acidic. Since on descending the group lattice energy decreases more rapidly than the hydration energy. What makes barium fluoride insoluble in water?
{BaF2 : ~~~1.7 g/L}$ $\ce{BeF2}$ itself is mentioned as infinitely soluble in water. Phosphates such as Ca3(PO4)2 and Ag3PO4 are frequently insoluble. See how other students and parents are navigating high school, college, and the college admissions process. Hey there! Barium fluoride is also a common, very fast (one of the fastest) scintillators for the detection of X-rays, gamma rays or other high energy particles. The solubility product constant for The solubility product constant for A: Ksp concept :Ksp : At normal temperature, if the solubility of a salt is 0.1mol / Lit then that salt Is it suspicious or odd to stand by the gate of a GA airport watching the planes? Exceptions Ag+, Pb2+, and (Hg2)2+- most sulfates are soluble. Free and expert-verified textbook solutions. Shreya G answered on July 16, 2021. 1 shows how to calculate the solubility effect of adding a strong acid to a solution of a sparingly soluble salt. New Questions About Fantasy Football Symbols Answered and Why You Must Read Every Word of This Report. Molecules where one end is negatively charged and the other is positively charged are considered polar, meaning that they have electrical poles. This is a useful factor in qualitative analysis. BaF2s Ba2+aq+2F-aq- s 2s. It is $\ce{CaF2}$. How do you calculate solubility in water? A saturated solution of BaF2 at 25C is prepared by equilibrating solid BaF2 with water. Question 19 Which of the following substances has the greatest solubility in water? She loves reading, the outdoors, and learning about new things.
Solved: a. Calculate the molar solubility of barium fluoride, BaF2 To learn more, see our tips on writing great answers. However, compounds that we know to be highly soluble, like salt, are likely to form solutions at various ratios; in this case, we will be able to determine how much solute and solvent is needed to form each solution, and if it's possible to form one at all. Question = Is C2Cl2polar or nonpolar ? Though I can tell this just by glancing at the rules, nothing takes away from the magic of watching chemical compounds break down and dissolve right before your eyes. Generally, the solute is a solid and the solvent is a liquid, such as our salt in water example above. Check out Tutorbase! Does Counterspell prevent from any further spells being cast on a given turn? Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a solid, liquid, or gaseous solvent.
A saturated solution of BaF2 at 25C is prepared by equilibr - Quizlet If you need more non-chemistry science guides, be sure to check out these guides about finding the density of water, defining commensalism, and how to calculate acceleration. Is BaF2 ( Barium fluoride ) Soluble or Insoluble in water ? So if we have two lead . Wikipedia says $\ce{BeF2}$ is highly soluble, whereas $\ce{CaF2}$ is insoluble. Good spectral range 4. The solubility-product constant for BaF2 is 1.7 x 10^-6 at 25 C. Lead two fluoride forms lead two plus ions and fluoride anions in a one to two mole ratio. However, sugar would have a low solubility in a nonpolar liquid like vegetable oil. . Chemistry Stack Exchange is a question and answer site for scientists, academics, teachers, and students in the field of chemistry. What is the molar solubility of barium fluoride ( BaF2 ) in water? Select the compounds that are always soluble in water (bolded are correct). As we see from our solubility rules, some substances are very soluble, while some are insoluble or have low solubility. Done on a Dell Dimension laptop computer with a Wacom digital tablet (Bamboo). The substance that is dissolved is called a solute, and the substance it is dissolving in is called a solvent. Sodium chloride contains Na, which is almost always soluble according to rule 1, and Cl, which is usually soluble according to rule 3. We use cookies to ensure that we give you the best experience on our website. Remember to keep your periodic tables handy, and pay close attention to the solubility rules in your next experiment. If there is more solute than is able to be dissolved, the excess separates from the solution and forms a precipitate. MathJax reference. H 2 O] is a sparingly soluble salt that is the other major component of kidney stones [along with Ca 3 (PO 4) 2 ]. 81 views Jul 19, 2022 Is BaF2 (Barium fluoride) soluble or insoluble in. Browse other questions tagged, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site. [10] Like CaF2, it is resilient to and insoluble in water. Although it is an ionic compound, it does not dissociate much into its ions in water, however a small amount does dissolve.When the small amount of BaF2 is dissolved in H2O (water) it will dissociate (dissolve) into Ba 2+ and F- ions. Which (if any) silver is soluble: Silver chloride AgCl, silver phosphate, Ag3 PO4, or silver fluoride, AgF? We walk you through the solubility constant (Ksp) and how to solve for it, explain how to balance chemical equations, and go over examples of physical vs chemical change here. See Answer Question: What is the molar solubility of barium fluoride (BaF2) in water? Compare the solubility in this case with that of BaF 2 in pure water. You will be able to accurately predict what combinations will lead to what results. Which is more soluble in water BaF 2 or BeF Total number of structural isomers of [Co(NH 3 ) 6 ] [Cr(CN) 6 ]. If we know that a substance is insoluble, it is likely that it would have excess solute, thus forming a precipitate.
Step 1: Molar solubility of BaF2 in pure water - studysmarter.us Answered: Determine the molar solubility of BaF2 | bartleby Answer = SiCl2F2 is Polar What is polarand non-polar? The solubility product Ksp of BaF2 is 1. . 2-. Most sulfate salts are soluble. How can you explain the solubility of BeF2? Taking IB instead? Knowing and following the solubility rules is the best way to predict the outcome of any given solution. The solubility of a substance is an entirely different property from the rate of solution, which is how fast it dissolves. Some will dissolve but only a small amount.These are some of the basic rules for solubility ( https://youtu.be/zffVKN6tm7k):Salts of:- Group I elements (Li+, Na+, K+, Cs+, Rb+) are- NH4+ (Ammonium ion) are soluble.- the nitrate ion (NO3-) are generally soluble.- of Cl-, Br-, and I- are soluble. BaF2(s) Ba2+(aq) + 2F-(aq) Because the state is going from Solid to aqueous. It is a colorless solid that occurs in nature as the rare mineral frankdicksonite. In general, the solubility of a substance depends on not only the energetic factors we have discussed but also the temperature and, for gases, the pressure. All rights reserved. Solutes typically will dissolve best in solvents that have the most molecular similarities. 1 What is the molar solubility of BaF2 in water? Is SbCl5 ( Antimony pentachloride ) polar or nonpolar ?
Solved 2) Determine the molar solubility of BaF2 in pure - Chegg It is based on the difference in solubility between silver chloride (AgCl;kSP = 1.610 - 10)and silver chromate (AgCrO4;KSP = 1.910 - 12) In using this method, one adds a small amount of CI- chromate ion to a solution with unknown chloride concentration. Site design / logo 2023 Stack Exchange Inc; user contributions licensed under CC BY-SA. It is very important that the rules on this list are followed in order, because if a rule seems to contradict another rule, the rule that comes first is the one that you follow. What is the solubility trend of alkaline earth metal fluorides? Screen capture done with Camtasia Studio 4.0. Our new student and parent forum, at ExpertHub.PrepScholar.com, allow you to interact with your peers and the PrepScholar staff. By clicking Accept All Cookies, you agree to the storing of cookies on your device to enhance site navigation, analyze site usage, and assist in our marketing efforts. H Pat Gillis, David W Oxtoby, Laurie J Butler, Question: The Mohr method is a technique for determining the amount of chloride ion in an unknown sample.
CHEM 2 MIDTERM Flashcards | Quizlet Determine whetherCaF2s (role="math" localid="1661513203101" Ksp=3.910-11) tends to precipitate from this mixture. BaF2, Kp = 1.5 x 10-6 Ca(OH)2, Ksp - 6,5 x 10-6 SrCros. The best answers are voted up and rise to the top, Not the answer you're looking for? It is a colorless solid that occurs in nature as the rare mineral frankdicksonite. Use MathJax to format equations. Generally, solutes are soluble in solvents that are most similar to them molecularly. For example, sugar is a polar solute, and absorbs very well in water. Study with our articles on every AP Chemistry practice test available and the ultimate AP Chem study guide. None of the above silver is soluble. However, the process of solubility is unique, and the rate at which it dissolves is not factored into the equation. Fluorides such as BaF2, MgF2, and PbF2 are frequently insoluble. Approved Other Related Questions on Inorganic Chemistry Solubility is the property of a solid, liquid, or gaseous chemical substance called solute to dissolve in a solid, liquid, or gaseous solvent. At 20C, for example, 177 g of NaI, 91.2 g of NaBr, 35.9 g of NaCl, and only 4.1 g of NaF dissolve in 100 g of water. How can we prove that the supernatural or paranormal doesn't exist? Beryllium fluoride is very soluble in water, owing to the high solvation energy of Be in forming $\ce{[Be(H2O)4]^2+}$. What is the molar solubility of calcium carbonate ( CaCO3) in water? The (aq) shows that they are aqueous dissolved in water.The equation for BaF2 ( Barium fluoride and H2O sometimes isnt considered a chemical reaction since it is easy to change the Ba 2+ and F- back to BaF2 (just let the H2O evaporate). Answer: B2 2-is a Diamagnetic What is Paramagnetic and Diamagnetic ? hbspt.cta._relativeUrls=true;hbspt.cta.load(360031, '21006efe-96ea-47ea-9553-204221f7f333', {"useNewLoader":"true","region":"na1"}); Carrie holds a Bachelors in Writing, Literature, and Publishing from Emerson College, and is currently pursuing an MFA. ACT Writing: 15 Tips to Raise Your Essay Score, How to Get Into Harvard and the Ivy League, Is the ACT easier than the SAT?
Solved What is the molar solubility of barium fluoride - Chegg Important exceptions to this rule include CaSO4, BaSO4, PbSO4, Ag2SO4 and SrSO4 . Polar solutes will dissolve better in polar solvents, and non-polar solutes will dissolve better in non-polar solvents. Even if it is a weaker conjugate base, why didn't this happen? [14] Another proposal is that polarisation of the electron core of the barium atom creates an approximately tetrahedral distribution of charge that interacts with the Ba-F bonds.[15]. When a solute is mixed with a solvent, there are three possible outcomes: If the solution has less solute than the maximum amount it is able to dissolve (the solubility), it is a dilute solution. Check out our top-rated graduate blogs here: PrepScholar 2013-2018. 1. 2.4K views 1 year ago In this video we will describe the equation BaF2 + H2O and write what happens when BaF2 is dissolved in water. Is BaF2 (Barium fluoride) soluble or insoluble in water?
Is CaF2 Soluble or Insoluble in Water? (CaF2 + H2O) - YouTube By measuring the volume of AgNO3 added before the appearance of the red silver chromate, one can determine the amount of originally present. Trying to understand how to get this basic Fourier Series, Acidity of alcohols and basicity of amines, Bulk update symbol size units from mm to map units in rule-based symbology. National Center for Biotechnology Information. By clicking Accept all cookies, you agree Stack Exchange can store cookies on your device and disclose information in accordance with our Cookie Policy. A solute is considered insoluble when they are unable to dissolve at a ratio greater than 10000:1. Correct option is C) Let s be the solubility of BaF 2 in BaNO 3 solution. Please take a site tour and familiarize yourself with how to typeset here. Exceptions: Ba2+, Ca2+, Pb2+, Ag+, Sr2+- most hydroxide salts are only slightly soluble. This compound is soluble. A Comprehensive Guide.
Estimate the solubility if Thallium thiocyanate in units of gram per 100ml of water. National Library of Medicine. Question: Is calcium oxidean ionic or covalent bond ? On the solubility table we can see that BaF2 (Barium fluoride ) is insoluble in water.Solubility Chart used in video: https://en.wikipedia.org/wiki/Solubility_chartBecause it is insoluble in water, we would expect that it would NOT dissociate into its ions.Solubility Resources:- Solubility Rules and the Solubility Table: https://youtu.be/zffVKN6tm7k- Net Ionic Equations: https://youtu.be/PXRH_IrN11Y- Finding the Charge on Ions: https://youtu.be/N4N1Njh7nCoWe could also just get some BaF2 and see if it dissolves in water, that would also tell us if it is soluble or insoluble.Based on the solubility rules and solubility chart we would expect Barium fluoride to be insoluble in water. Luckily, solubility follows a list of rules that helps us determine how soluble a substance is, like how likely that salt is to dissolve into that water (sneak peek- its very likely). Magnesium fluoride is highly insoluble in water (0.0076 g/100 mL) at 18C [151]. Although it is an ionic compou. A compound's molar solubility in water can be calculated from its K value at 25C. Thalliumthiocyanate (2TlSCN) is only slightly in water. How to Market Your Business with Webinars. Preparing for the AP Chemistry test? Calculate the solubility product, Ksp, of both compounds. Its solubility in water at 25C is 7.36 10 4 g/100 mL. Creative Commons Attribution/Non-Commercial/Share-Alike. Thus, AgCl, PbBr2, and Hg2Cl2 are insoluble. The resulting substance is called a solution. Sure, I'll keep that in mind next time and thanks @BuckThorn. The solubility-product constant for BaF2 is 1.7 x 10^-6 at 25 C. One of the first science experiments I remember was adding salt to a cup of water and waiting eagerly for it to dissolve. Ksp = 2.2 x 10-5 Ag2SO4, Ksp - 1.5 x 10-5 Zn(103)2, Ksp = 3.9 x 10-6 This problem has been solved! She worked in book publishing for several years, and believes that books can open up new worlds. PubChem . Other factors that affect solubility are pressure and temperature. The other fluorides MF2 are are all almost insoluble. Therefore whatever little solubility these fluorides have that increase down the group.
Worked example: Calculating solubility from K - Khan Academy Answer = C2H6O is Polar What is polarand non-polar? Except where otherwise noted, data are given for materials in their, "Crystran Ltd. Optical Component Materials", "Ab initio model potential study of the equilibrium geometry of alkaline earth dihalides: MX2 (M=Mg, Ca, Sr, Ba; X=F, Cl, Br, I)", https://en.wikipedia.org/w/index.php?title=Barium_fluoride&oldid=1141527881, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 25 February 2023, at 14:28.